Averiguá que "collation" estás usando. Las que terminan en _ci ("case
insensitive", mayúsculas/minúsculas son indisitintas) son las que necesitás.
Cita: By default, MySQL searches are not case sensitive (although there are some character sets that are never case insensitive, such as czech). This means that if you search with col_name LIKE 'a%', you get all column values that start with A or a. If you want to make this search case sensitive, make sure that one of the operands has a case sensitive or binary collation. For example, if you are comparing a column and a string that both have the latin1 character set, you can use the COLLATE operator to cause either operand to have the latin1_general_cs or latin1_bin collation. For example:
col_name COLLATE latin1_general_cs LIKE 'a%'
col_name LIKE 'a%' COLLATE latin1_general_cs
col_name COLLATE latin1_bin LIKE 'a%'
col_name LIKE 'a%' COLLATE latin1_bin
If you want a column always to be treated in case-sensitive fashion, declare it with a case sensitive or binary collation. See Section 13.1.5, “CREATE TABLE Syntax”.
http://dev.mysql.com/doc/refman/5.0/...nsitivity.html