Ya intentaste así?
Código PHP:
Ver original<?php
$xml = '<ICE-interface xsi:noNamespaceSchemaLocation="http://xxxxxxxxxx/xsd/files.index.xsd">
<files.index Generated="2012335566">
<file path="/exports//ESP/468893.xml" Product_ID="468893" Updated="20120307013032" Quality="ICE" Supplier_id="1" Prod_ID="CB568331EE" Catid="377" On_Market="1" Model_Name=" CB568331EE " Product_View="7934094" HighPic="http://images.xxxxxxxx.xxx/img/norm/high/468893-HP.jpg" HighPicSize="35979" HighPicWidth="400" HighPicHeight="400">
</file>
</files.index>
</ICE-interface>';
$sxe = new SimpleXMLElement($xml);
echo $sxe->{'files.index'}->file['HighPic']; //http://images.xxxxxxxx.xxx/img/norm/high/468893-HP.jpg
o algo así?
Código PHP:
Ver original<?php
$xml = '<ICE-interface xsi:noNamespaceSchemaLocation="http://xxxxxxxxxx/xsd/files.index.xsd">
<files.index Generated="2012335566">
<file path="/exports//ESP/468893.xml" Product_ID="468893" Updated="20120307013032" Quality="ICE" Supplier_id="1" Prod_ID="CB568331EE" Catid="377" On_Market="1" Model_Name=" CB568331EE " Product_View="7934094" HighPic="http://images.xxxxxxxx.xxx/img/norm/high/468893-HP.jpg" HighPicSize="35979" HighPicWidth="400" HighPicHeight="400">
</file>
</files.index>
</ICE-interface>';
$sxe = new SimpleXMLElement($xml);
foreach ($sxe->{'files.index'}->file->attributes() as $c => $v) {
echo "$c => $v <br />";
}
Cita: path => /exports//ESP/468893.xml
Product_ID => 468893
Updated => 20120307013032
Quality => ICE
Supplier_id => 1
Prod_ID => CB568331EE
Catid => 377
On_Market => 1
Model_Name => CB568331EE
Product_View => 7934094
HighPic => http://images.xxxxxxxx.xxx/img/norm/high/468893-HP.jpg
HighPicSize => 35979
HighPicWidth => 400
HighPicHeight => 400