Generar un obj array

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Ya logre lo que buscaba :)

Código PHP:

$items = array();
$payers = array();
 
 
$item = array (
    "id" => "item-ID-1234",
    "title" => "Multicolor kite",
    "quantity" => 1,
    "currency_id" => "ARS", // Available currencies at: https://api.mercadopago.com/currencies
    "picture_url" => "https://www.mercadopago.com/org-img/MP3/home/logomp3.gif",
    "description" => "Item description",
    "category_id" => "art", // Available categories at https://api.mercadopago.com/item_categories
    "unit_price" => 10.00
);
 
$payer = array (
    "name" => "user-name",
    "surname" => "user-surname",
    "email" => "[email protected]",
    "date_created" => "2015-06-02T12:58:41.425-04:00",
    "phone" => array(
        "area_code" => "11",
        "number" => "4444-4444"
    ),
    "identification" => array(
        "type" => "DNI",
        "number" => "12345678"
    ),
    "address" => array(
        "street_name" => "Street",
        "street_number" => 123,
        "zip_code" => "5700"
    ) 
);
 
$items [] = $item;
$payers [] = $payer;
 
$data = array(
    "items" => $items,
    "payer" => $payers
    );